Mercury Selective Electrode
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چکیده
منابع مشابه
Mercury(II) ion-selective electrodes based on p-tert-butyl calix[4]crowns with imine units.
A PVC membrane incorporating p-tert-butyl calix[4]crown with imine units as an ionophore was prepared and used in an ion-selective electrode for the determination of mercury(II) ions. An electrode based on this ionophore showed a good potentiometric response for mercury(II) ions over a wide concentration range of 5.0 x 10(-5) - 1.0 x 10(-1) M with a near-Nernstian slope of 27.3 mV per decade. T...
متن کاملA mercury(II) ion-selective electrode based on N,N-dimethylformamide-salicylacylhydrazone as a neutral carrier.
A new PVC membrane mercury(II) ion electrode based on N,N-dimethylformamide-salicylacylhydrazone (DMFAS) as an ionophore is described, which shows excellent potentiometric response characteristics and displays a linear log[Hg(2+)] versus EMF response over a wide concentration range between 6.2 x 10(-7) and 8.0 x 10(-2) M with a Nerstian slope of 29.6 mV per decade and a detection limit of 5.0 x...
متن کاملA multi-technique surface study of the mercury(II) chalcogenide ion-selective electrode in saline media.
X-ray photoelectron spectroscopy (XPS), secondary ion mass spectrometry (SIMS), rotating disc electrode-electrochemical impedance spectroscopy (RDE-EIS) and synchrotron radiation-grazing incidence X-ray diffraction (SR-GIXRD) have been used to study the response mechanism of the mercury(II) chalcogenide ion-selective electrode (ISE) in saline media. XPS and SIMS have shown that the chalcogenide...
متن کاملSelective Determination of Trace-Bismuth by Extraction-Differential Pulse Polarography in Non-Aqueous Media
The voltammetric characteristics of bismuth(III)-oxinate in chloroform at the mercury electrode were investigated and a quasi-reversible behavior for Bi(III) oxinate reduction was confirmed. Preceded by the extraction of Bi(III) oxinate in chloroform, differential pulse polarography was developed in the extracts for determination of the trace-bismuth. The linear range of the calibration gra...
متن کاملConstruction of a Carbon Paste Electrode Based on Novel Thiolated Ligand Capped Gold Nanoparticles for Determination of Trace Amounts of Mercury(II)
In the present study, a simple electrochemical sensor for trace determination of Hg(II) ions in aqueous solutions was introduced. The proposed sensor was designed by incorporation of the 4-methyl-piperidine-carbodithioate capped gold nanoparticles (GNPs) into the carbon paste electrode (CPE), which provides a remarkably improved sensitivity for stripping voltammetric determination of Hg(II). Di...
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